Bad vibrations

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Bad vibrations? A brief explanation of the heat trapping properties of CO2

I'm pickin' up good vibrations
She's giving me the excitations
Brian Wilson / Mike Love / The Beach Boys

Basic mechanism for the absorption of radiation

When radiation (visible light, infra red, ultra violet …) impacts an atom or a molecule, if the frequency of that radiation matches the natural resonant frequency of the molcule energy it is momentarily absorbed, 'exciting' the molecule into a higher energy state. After a short time the same amount of energy is re-radiated and the molecule returns to its normal or 'ground' state. Although the radiation is only 'borrowed' this capture/release is nevertheless an absorption mechanism, because the re-radiation occurs in a random direction so in the simplified 1-dimensional case there would be a 50% probability the radiation were sent back in the direction it came from. It can be understood that for a sufficiently deep and concentrated layer of molecules, this scattering and attenuation could amount to absorption.